Investigation of Leaching Kinetics of Smithsonite Ore

Authors

  • Bunyamin Dönmez Department of Chemical Engineering, Atatürk Üniversity, 25240 Erzurum, TURKEY
  • Feride Ebru Eti Department of Chemical Engineering, Atatürk Üniversity, 25240 Erzurum, TURKEY
  • Oral Laçin Department of Chemical Engineering, Atatürk Üniversity, 25240 Erzurum, TURKEY
Abstract:

The leaching kinetics of smithsonite ore in acetic acid solutions, an environmental friend, and natural reagent was investigated. The influence of parameters such as reaction temperature, particle size, solid-liquid ratio and acid concentration was studied in order to reveal the leaching kinetics of smithsonite ore. In this study, experimental and statistical methods were carried out in order to analyze the kinetics data to investigate a kinetics model which describes the dissolution.  The results indicate that the unreacted shrinking core model for fluid-solid heterogeneous reactions was favorable for the leaching process. The apparent activation energy of the leaching process was found as 74 kJ/ mol. It was determined that the leaching rate of smithsonite was controlled by the chemical reaction below.

Upgrade to premium to download articles

Sign up to access the full text

Already have an account?login

similar resources

Investigation of leaching kinetics of zinc from a low-grade ore in organic and inorganic acids

The leaching kinetics of a low-grade zinc oxide ore in different acid media was investigated with respect to the experimental variables including acid concentration, temperature, liquid to solid (L/S) ratio, and stirring speed. The results obtained showed that the leaching reagent concentration and the reaction temperature exerted significant effects on the extraction of zinc, whereas the L/S r...

full text

Kinetics of chemical leaching of chalcocite from low-grade copper ore: size-distribution behavior

Kinetics of the chemical leaching of chalcocite from a low-grade copper ore in a ferric sulfate medium was investigated using the constrained least square optimization technique. The experiments were carried out for different particle sizes in both the reactor and column at constant Eh, pH, and temperature. The leaching rate increased with increase in the temperature. About 50% of the Cu recove...

full text

Fungal Leaching of Manganese Ore

Bioleaching is technologically feasible for extraction of manganese from low grade ores (containing manganese less than 35% by weight). The principle involves the non-enzymatic reduction of pyrolusite [Mn(IV) oxides] to +2 oxidation state by fungi with the production of metabolites such as oxalic acid and citric acid. In the present investigation, a fungal strain, Penicillium citrinum was isola...

full text

Effect of Mechanical Activation on the Kinetics of Ammoniacal Thiosulfate Leaching of a Refractory Oxide Gold Ore

The effect of mechanical activation on the kinetics of ammoniacal thiosulfate leaching of a refractory oxide gold ore containing 2.8 ppm Au was investigated. The gold extraction of 99.81% was achieved by 16 h leaching of a sample mechanically activated for 60 minutes. The gold extraction observed for a similar reference sample without mechanical activation was only 55%. Studies revealed that le...

full text

investigation of thermal comfort properties of woven sport fabric using blend of estabragh fibers

امروزه لباس در نظر ورزشکاران و کسانی که برای اوقات فراغت خود و یا برای رسیدن به اندامی متعادل، ورزش می کنند؛ بسیار با اهمیت است. احساس مطلوب از لباس در زمره خصوصیات راحتی پوشش می باشد. خصوصیات انتقال رطوبت لباس، در ارزیابی راحتی حسی و حرارتی منسوجات تولید شده از آن ها بسیار مهم است. هدف از این تحقیق، معرفی پارچه جدید است که متشکل از الیاف استبرق با خواص منحصر به فرد می باشد. استبرق لیف طبیعی تو...

Leaching Kinetics of Stibnite in Sodium Hydroxide

Spherical pellets of antimony sulphide were dissolved in 1 molar sodium hydroxide solutions at different temperatures. It was found that the shrinking core with ash layer model could satisfactorily explain the dissolution process. Using this model it was found that initially the rate controlling step is a chemical reaction with activation energy of 10.2 kJ/mol. As the ash layer builds up, diffu...

full text

My Resources

Save resource for easier access later

Save to my library Already added to my library

{@ msg_add @}


Journal title

volume 37  issue 1

pages  205- 212

publication date 2018-02-01

By following a journal you will be notified via email when a new issue of this journal is published.

Hosted on Doprax cloud platform doprax.com

copyright © 2015-2023